A halogen bond-donor amino acid for organocatalysis in water
| Autor: | Luisa Lascialfari, Alberto Milani, Nicola Demitri, Greta Bergamaschi, Pierangelo Metrangolo, Alessandro Gori, Andrea Pizzi, Maria Isabel Martinez Espinoza |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
inorganic chemicals
010402 general chemistry 01 natural sciences Catalysis supramolecular chemistry Catalytic effect Polymer chemistry Materials Chemistry organocatalysis chemistry.chemical_classification Halogen bond Aqueous solution 010405 organic chemistry Metals and Alloys General Chemistry 3. Good health 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Amino acid chemistry Organocatalysis Halogen Ceramics and Composites halogen bond amino acid |
| Zdroj: | Chemical communications (Lond., 1996, Print) 54 (2018): 10718–10721. doi:10.1039/c8cc06010j info:cnr-pdr/source/autori:Greta Bergamaschi, *a Luisa Lascialfari, ?a Andrea Pizzi, a Maria Isabel Martinez Espinoza, a Nicola Demitri, b Alberto Milani, a Alessandro Gori *c, Pierangelo Metrangolo a/titolo:A halogen bond-donor amino acid for organocatalysis in water/doi:10.1039%2Fc8cc06010j/rivista:Chemical communications (Lond., 1996, Print)/anno:2018/pagina_da:10718/pagina_a:10721/intervallo_pagine:10718–10721/volume:54 |
| DOI: | 10.1039/c8cc06010j |
| Popis: | Herein we report a halogen bond-donor amino acid, 4-iodotetrafluorophenylalanine, which behaves as a catalyst for the aqueous synthesis of bis-(heterocyclic)methanes. We also provide experimental evidence that halogen bonding is a plausible explanation for the observed catalytic effect. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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