(Digital Presentation) Effect of Compression Pressure on Water Removal and Power Generation Performance of PEFC with Modified Electrode/Channel Structure

Autor: Reiya Kaneko, Tatsuki Furukawa, Kosuke Nishida
Rok vydání: 2022
Zdroj: ECS Transactions. 109:127-133
ISSN: 1938-6737
1938-5862
DOI: 10.1149/10909.0127ecst
Popis: Water flooding in cathode electrodes of polymer electrolyte fuel cells (PEFCs) is a critical issue that must be solved for achieving high efficiency and high power density operations. To alleviate this problem, it is necessary to design the optimum electrode/channel structure for actively removing liquid water from the porous media to the flow channel. In the previous studies, Okuhata et al. [1] revealed that the introduction of penetration holes to gas diffusion electrodes (GDEs) effectively promotes the water discharge and improves the limiting current density. Nishida et al. [2] investigated the effect of channel hydrophilization on the water behavior in the cathode of an operating cell using the cross-sectional visualization technique. It was found that the hydrophilization of cathode channels encourages the water suction from the gas diffusion layer (GDL) to the channel and enhances the oxygen diffusibility to the catalyst layer (CL). Our research group has proposed a novel hybrid electrode/channel structure combining the electrode perforation and channel hydrophilization and has investigated its effect on the improvements of water drainage and cell performance. In this study, we directly visualized the liquid water distribution in the cathode GDL of a customized PEFC with the hybrid electrode/channel structure using X-ray imaging and evaluated the transient response of cell voltage under the constant-current operations. Furthermore, the influence of compression pressure on the water behavior in the perforated GDL and the performance characteristics of the customized cell was also examined. For the X-ray investigation, we fabricated a specialized miniature fuel cell with the effective electrode area of 2.88 cm2. The membrane electrode assembly (MEA) was sandwiched between two carbon separators with a single-serpentine flow field (number of channels: 7, channel width: 1.0 mm, depth: 1.0 mm, total length: 88.5 mm). Fig. 1 shows a schematic cross-sectional view on the cathode side of the experimental cell. Since the cathode GDL is irradiated with X-ray beam in the in-plane direction, the through-plane distributions of water can be observed in the GDL under the 4th channel and under the land between the 3rd and 4th channel. To promote the water discharge from the fine porous media, a penetration groove (width: 300 μm, length: 11 mm) was installed into the GDL, MPL and CL and positioned along the right sidewall of the 4th channel. The channel walls on the cathode side were coated with the silica-based hydrophilic solvent. The contact angle of water on the hydrophilized channel is 9.8o. In the hybrid electrode/channel structure, liquid water accumulated in the CL and MPL is firstly discharged into the large groove in the in-plane direction. Subsequently, water droplets gathered in the groove are grown up and attached to the hydrophilized channel walls. The droplets are spread out on the hydrophilic sidewalls and the liquid films are moved upward. Fig. 2 presents the distributions of water saturation in the perforated GDL of the customized cell assembled under two different compression pressures of 0.5 and 1.0 MPa. The current density was increased stepwise from 0.14 to 1.02 A/cm2 for 8 min under the room temperature and non-humidification condition. All images were captured at t=8 min after starting the operation. Dry hydrogen (stoichiometry: 1.5@2.0A/cm2) and oxygen (stoichiometry: 3.0@2.0A/cm2) were supplied to the anode and cathode in the counter-flow arrangement. It was found that the introduction of the hybrid structure effectively decreases the water saturation around the groove due to the in-plane water discharge. The reduction of saturation under the land is much less than under the channel because the strong mechanical compression crushes the pore structure under the land regions and suppresses the water transport. In addition, the low-saturation region of 28% or less around the groove is enlarged with a decrease in compression pressure. The low compression pressure maintains the relatively large porosities in diffusion media and facilitates the water removal. References: [1] G. Okuhata, et al., ECS Trans., 58(1), 1047 (2013). [2] K. Nishida, et al., ECS Trans., 69(17), 1121 (2015). Figure 1
Databáze: OpenAIRE
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