Significantly improved shear, dynamic-mechanical, and mode II fracture performance of seawater aged basalt/epoxy composites: The impact of halloysite nanotube reinforcement

Autor: Ahmet Avcı, Volkan Eskizeybek, Hasan Ulus, Halil Burak Kaybal
Rok vydání: 2021
Předmět:
Toughness
Materials science
Computer Networks and Communications
020209 energy
Composite number
Dynamic mechanical analysis (DMA)
02 engineering and technology
engineering.material
Seawater aging
Halloysite
Biomaterials
Mode II delamination toughness (GIIC)
0202 electrical engineering
electronic engineering
information engineering

Shear strength
Halloysite nanotubes (HNTs)
Composite material
Civil and Structural Engineering
Fluid Flow and Transfer Processes
chemistry.chemical_classification
Basalt fiber (BF)
Mechanical Engineering
020208 electrical & electronic engineering
Delamination
Metals and Alloys
Epoxy
Polymer
Epoxy (EP)
Engineering (General). Civil engineering (General)
Electronic
Optical and Magnetic Materials

chemistry
Hardware and Architecture
Basalt fiber
visual_art
engineering
visual_art.visual_art_medium
TA1-2040
Zdroj: Engineering Science and Technology, an International Journal, Vol 24, Iss 4, Pp 1005-1014 (2021)
ISSN: 2215-0986
DOI: 10.1016/j.jestch.2021.01.005
Popis: The primary concern of fiber-reinforced polymers (FRPs) subjected to seawater environment is losing their initial mechanical performance since water can diffuse into the composite and deteriorates the fiber-matrix interface. Recent studies related to aging performance in the seawater environment have shown that introducing halloysite nanotubes (HNTs) into the polymer matrix offers a combination of an efficient barrier effect and an improved fiber-matrix interface. Hereupon, the principal objective of this study was to experimentally investigate the impact of HNTs on shear and mode II fracture performances of the seawater aged basalt fiber (BF) reinforced epoxy (EP) composites. After six months of aging in seawater, the findings indicated that HNTs reinforced multi-scale composites exhibited 34 and 46% higher shear strength and mode II delamination toughness compared to the neat specimens. Moreover, according to the dynamic-mechanical analysis, higher glass transition temperatures (8%) were obtained for the multi-scale composites. The reduction in mechanical performances induced by fiber-matrix interfacial degradation was also confirmed by scanning electron microscopy analysis. Chemical deterioration of the polymer matrix was explored by Raman spectroscopy to reveal the efficiency of HNTs induced barrier effect. As a result of these investigations, HNT modified BF/EP multi-scale composites were offered for future advanced engineering applications.
Databáze: OpenAIRE