Probing the local structure of Prussian blue electrodes by 113Cd NMR spectroscopy
| Autor: | Masashi Okubo, Alexandrine Flambard, Akira Sugahara, Atsuo Yamada, S De, Rodrigue Lescouëzec |
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| Přispěvatelé: | Institut Parisien de Chimie Moléculaire (IPCM), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Department of Chemical System Engineering, The University of Tokyo, The University of Tokyo (UTokyo), Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2017 |
| Předmět: |
Prussian blue
Reaction mechanism Chemistry Intercalation (chemistry) Analytical chemistry [CHIM.MATE]Chemical Sciences/Material chemistry 02 engineering and technology Nuclear magnetic resonance spectroscopy 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Local structure 0104 chemical sciences 3. Good health Inorganic Chemistry chemistry.chemical_compound TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY Electrode 0210 nano-technology |
| Zdroj: | Dalton Transactions Dalton Transactions, 2017, 46 (19), pp.6159-6162. ⟨10.1039/C7DT00728K⟩ Dalton Transactions, Royal Society of Chemistry, 2017, 46 (19), pp.6159-6162. ⟨10.1039/C7DT00728K⟩ |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c7dt00728k |
| Popis: | International audience; We demonstrate that 113Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li+ intercalation, providing an atomic-scale insight into the reaction mechanism. |
| Databáze: | OpenAIRE |
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