Phosphorus pentoxide/metal chloride mediated efficient and facile catalytic conversion of fructose into 5-hydroxymethylfurfural
| Autor: | Songyan Jia, Ma Jiao, Z. Conrad Zhang, Zhanwei Xu, He Xinjun, Kangjun Wang |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Metal chloride
010405 organic chemistry General Chemical Engineering Fructose General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry 5-hydroxymethylfurfural Yield (chemistry) Selectivity Phosphorus pentoxide Nuclear chemistry |
| Zdroj: | RSC Advances. 8:32533-32537 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c8ra07027j |
| Popis: | Phosphorus pentoxide (P2O5)/metal chloride mixtures could significantly improve 5-HMF yield and selectivity for the catalytic conversion of fructose under mild conditions, whereas neither P2O5 nor tested metal chloride alone gave reasonable performances. A maximum 5-HMF yield of 75% with ∼85% selectivity could be achieved within 30 min at 80 °C. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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