Synthesis and ligand properties towards gold and silver of the ferrocenylamidobenzimidazole ligand

Autor: Maria José Calhorda, Paulo J. Costa, Antonio Laguna, Susana Quintal, M. Dolores Villacampa, M. Concepción Gimeno, Paulo N. Martinho
Rok vydání: 2006
Předmět:
Zdroj: Digital.CSIC. Repositorio Institucional del CSIC
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ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2006.06.025
Popis: 8 pages, 4 figures, 5 tables.
The treatment of FcCOCl (Fc = (C5H5)Fe(C5H4)) with aminobenzimidazole in 1:1 or 2:1 ratio gives the ferrocenyl-amido derivatives FcCO(benzimNH2) or (FcCO)2(NHbenzim), respectively. The reactivity of FcCO(benzimNH2) with silver or gold complexes has been studied. The reaction with the basic gold compounds [Au(acac)(PPh3)] or [O(AuPPh3)3]ClO4 occurs with deprotonation of the NH2 group and coordination of one or three gold(phosphine) fragments. The treatment of this ligand with silver compounds, such as Ag(OTf) or [Ag(OTf)(PPh3)], gives the complexes of stoichiometry [Ag(OTf)L] or [Ag(OTf)(PPh3)L]. The ligand FcCO(benzimNH2) and the complex [Ag(OTf){FcCO(benzimNH2)}(PPh3)] have been characterized by X-ray diffraction studies. DFT calculations were performed on models of this dimeric silver complex and showed that dimerization is energetically favourable, because Ag(I) achieves a four coordination environment, despite some bonds being relatively weak.
This work was supported by the Ministerio de Educación y Ciencia-FEDER (No. CTQ2004-05495-C02-01). We thank the Acción Integrada HP20030147 and Acção Integrada E-31/04. PJC acknowledges FCT for Grant (SFRH/BD/10535/2002) and S. Quintal for Grant (SFRH/BPD/11463/2002).
Databáze: OpenAIRE
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