Dioxygen Activation by Laccases: Green Chemistry for Fine Chemical Synthesis
| Autor: | Cynthia Romero-Guido, Eduardo Torres, Antonino Baez |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
0301 basic medicine
Green chemistry laccases lcsh:Chemical technology 01 natural sciences Catalysis lcsh:Chemistry 03 medical and health sciences chemistry.chemical_compound Oxidizing agent lcsh:TP1-1185 Phenols Physical and Theoretical Chemistry Laccase 010405 organic chemistry Chemistry Substrate (chemistry) enzymatic oxidation Combinatorial chemistry enzymatic dioxygen activation 0104 chemical sciences pharmaceutical synthesis 030104 developmental biology lcsh:QD1-999 Fine chemical Selectivity |
| Zdroj: | Catalysts, Vol 8, Iss 6, p 223 (2018) |
| ISSN: | 2073-4344 |
| DOI: | 10.3390/catal8060223 |
| Popis: | Laccases are enzymes with attractive features for the synthesis of fine chemicals. The friendly reaction conditions of laccases and their high conversion and selectivity make them particularly suitable for green methods of synthesis. In addition, laccases are enzymes with broad substrate variability, ease of production, and no need of cofactors or aggressive oxidizing agents. Among molecules oxidized by laccases are polycyclic aromatic hydrocarbons, azo dyes, pesticides, phenols, and pharmaceuticals. This article reviews the laccase-mediated oxidation of fine chemicals for the production of biologically active compounds. The main aspects of the enzymatic oxidation are summarized; potentials and limitations are identified and proposals to develop more robust catalysts are analyzed. |
| Databáze: | OpenAIRE |
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