Intersystem Crossing Mediated by Photoinduced Intramolecular Charge Transfer: Julolidine−Anthracene Molecules with Perpendicular π Systems

Autor:	Amy M. Scott, Mark A. Ratner, Thea M. Wilson, Michael R. Wasielewski, Sarah M. Mickley, Annie Butler Ricks, Zachary E.X. Dance
Rok vydání:	2008
Předmět:	Anthracene Dihedral angle Photochemistry law.invention Photoexcitation chemistry.chemical_compound Intersystem crossing chemistry Chemical physics law Intramolecular force Single bond Physical and Theoretical Chemistry Electron paramagnetic resonance Julolidine
Zdroj:	The Journal of Physical Chemistry A. 112:4194-4201
ISSN:	1520-5215 1089-5639
DOI:	10.1021/jp800561g
Popis:	Time-resolved electron paramagnetic resonance studies show that the primary mechanism of triplet formation following photoexcitation of julolidine-anthracene molecules linked by a single bond and having perpendicular pi systems is a spin-orbit, charge-transfer intersystem crossing mechanism (SOCT-ISC). This mechanism depends on the degree of charge transfer from julolidine to anthracene, the dihedral angle (theta1) between their pi systems, and the magnitude of the electronic coupling between julolidine and anthracene. We compare 4-(9-anthracenyl)-julolidine with the more sterically encumbered 4-(9-anthracenyl)-3,5-dimethyljulolidine and find that fixing theta1 congruent with 90 degrees serves to enhance SOCT-ISC by increasing the change in orbital angular momentum accompanying charge transfer. Given that the requirements for the SOCT-ISC mechanism are quite general, we expect it to occur in a variety of electron donor-acceptor systems.
Databáze:	OpenAIRE
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