A Straight Forward Route for the Development of Metal–Organic Frameworks Functionalized with Aromatic −OH Groups: Synthesis, Characterization, and Gas (N2, Ar, H2, CO2, CH4, NH3) Sorption Properties

Autor:	Pantelis N. Trikalitis, Pantelis Xydias, Christos D. Malliakas, Ioannis Spanopoulos
Rok vydání:	2013
Předmět:	Inorganic Chemistry Chemistry Polymer chemistry Organic chemistry Metal-organic framework Sorption Physical and Theoretical Chemistry Selectivity
Zdroj:	Inorganic Chemistry. 52:855-862
ISSN:	1520-510X 0020-1669
Popis:	A facile and general methodology for the development of metal-organic frameworks (MOFs) functionalized with pendant, aromatic hydroxyl (-OH) groups is presented. Extensive gas-sorption studies in representative and important MOFs functionalized with free aromatic -OH groups such as the IRMOF-8 and DUT-6 (or MOF-205), denoted here as 1 and 2, revealed a high CO(2)/CH(4) selectivity for 1 (13.6 at 273 K and 1 bar) and a high NH(3) uptake of 16.4 mol kg(-1) at 298 K and 1 bar for 2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d5691e06aabe352aae9244eba9833c74 https://doi.org/10.1021/ic302010e Zobrazit plný text záznamu