A Straight Forward Route for the Development of Metal–Organic Frameworks Functionalized with Aromatic −OH Groups: Synthesis, Characterization, and Gas (N2, Ar, H2, CO2, CH4, NH3) Sorption Properties
Autor: | Pantelis N. Trikalitis, Pantelis Xydias, Christos D. Malliakas, Ioannis Spanopoulos |
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Rok vydání: | 2013 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 52:855-862 |
ISSN: | 1520-510X 0020-1669 |
Popis: | A facile and general methodology for the development of metal-organic frameworks (MOFs) functionalized with pendant, aromatic hydroxyl (-OH) groups is presented. Extensive gas-sorption studies in representative and important MOFs functionalized with free aromatic -OH groups such as the IRMOF-8 and DUT-6 (or MOF-205), denoted here as 1 and 2, revealed a high CO(2)/CH(4) selectivity for 1 (13.6 at 273 K and 1 bar) and a high NH(3) uptake of 16.4 mol kg(-1) at 298 K and 1 bar for 2. |
Databáze: | OpenAIRE |
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