Two isostructural carboranes: 3-phenyl-1,2-dicarba-closo-dodecaborane(12) and 1-phenyl-1,7-dicarba-closo-dodecaborane(12)

Autor:	E. A. Chernyshev, Mikhail Yu. Antipin, Gennadii V. Grintselev-Knyazev, V. N. Kirin, S. P. Knyazev, Konstantin A. Lyssenko
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Crystallography Molecular geometry chemistry Stereochemistry Substituent Carborane Molecule General Medicine Crystal structure Isostructural General Biochemistry Genetics and Molecular Biology
Zdroj:	Acta crystallographica. Section C, Crystal structure communications. 57(Pt 7)
ISSN:	0108-2701
Popis:	Two phenyl-substituted carboranes, 3-phenyl-1,2-dicarba-closo-dodecaborane(12), C8H16B10, (I), and 1-phenyl-1,7-dicarba-closo-dodecaborane(12), C8H16B10, (II), were found to be isostructural. Comparison of the bond angles at the ipso-C atoms of the phenyl substituent for (I) and (II) [117.71 (3) and 118.45 (10) degrees, respectively] indicates that electron donation of the carborane cage for B- and C-substituted carboranes is different.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d55a71ea57ed8d49c60b33c9cc61302c https://pubmed.ncbi.nlm.nih.gov/11443255 Zobrazit plný text záznamu Plný text