Matrix-isolation infrared spectra of HOOBr and HOBrO produced upon VUV light irradiation of HBr/O2/Ne system

Autor:	Kazuhiko Shibuya, Nobuyuki Akai, Daisuke Wakamatsu, Akio Kawai, Takeo Yoshinobu
Rok vydání:	2010
Předmět:	Matrix (chemical analysis) Vacuum ultraviolet Chemistry Atmospheric chemistry Photodissociation Analytical chemistry Matrix isolation General Physics and Astronomy Infrared spectroscopy Light irradiation Reaction intermediate Physical and Theoretical Chemistry Photochemistry
Zdroj:	Chemical Physics Letters. 499:117-120
ISSN:	0009-2614
Popis:	Vacuum ultraviolet (VUV) light photolysis of an HBr/O 2 mixture in a Ne matrix has produced HO 2 Br isomers (HOOBr and HOBrO), which are important reaction intermediates in atmospheric chemistry. The observed bands have been assigned with an aid of a quantum chemical calculation at CCSD/aug-cc-pVDZ. These assignments have been confirmed by the experimental results using isotopic species of 18 O 2 or DBr. Their characteristic bands are discussed in comparison with those of HOOCl and HOClO from an HCl/O 2 mixture [7] . Both HOOBr and HOBrO are found to be photolyzed with the UV light below 385 nm.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d52e38faab597fd7a5092101ab994625 https://doi.org/10.1016/j.cplett.2010.09.039 Zobrazit plný text záznamu Full Text from ScienceDirect