Isotope effects in the metastable decay of Ne2 +

Autor:	K. Gluch, Tilmann D. Märk, S. Matt-Leubner, R. Parajuli, Juraj Fedor, Paul Scheier, Olof Echt
Rok vydání:	2007
Předmět:	Neon chemistry Metastability Kinetic isotope effect chemistry.chemical_element Atomic physics Kinetic energy Atomic and Molecular Physics and Optics Dissociation (chemistry) Electron ionization Isotopomers Ion
Zdroj:	ResearcherID
ISSN:	1434-6079 1434-6060
DOI:	10.1140/epjd/e2007-00105-x
Popis:	Neon dimer ions undergo spontaneous dissociation (metastable decay) several microseconds after formation by electron impact ionization of neon clusters. In this contribution we compare the kinetic energy release distribution (KERD) of the previously reported isotopomer 20Ne2 + with that of 22Ne2 +. The heavy isotopomer shows the same two components in the KERD as the lighter ones. However, the high-energy component that is due to electronic pre-dissociation is reduced in intensity. The decrease is attributed to a reduced predissociation rate from the II(1/2u) state into I(3/2u).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d4c9baf33487c14d64ad410c1c7fff41 https://doi.org/10.1140/epjd/e2007-00105-x Zobrazit plný text záznamu Plný text ve formátu PDF