9-Methyl-9-nitro-10-nitromethylene-9,10-dihydroanthracene. The First Isolation of a Proposed Intermediate for the Side-chain Nitration of Arenes under Heterolytic Conditions

Autor:	Toshimi Katayama, Emiko Kimura, Takuji Ogawa, Hitomi Suzuki
Rok vydání:	1987
Předmět:	chemistry.chemical_classification Anthracene Nitro compound General Chemistry DABCO 9 10-Dihydroanthracene Medicinal chemistry Heterolysis chemistry.chemical_compound chemistry Nitric acid Nitration Nitro Organic chemistry
Zdroj:	Chemistry Letters. 16:979-982
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1987.979
Popis:	Reaction of 9-methy 1-10-nitromethylanthracene with nitric acid in dichloromethane at low temperatures followed by treatment with DABCO gave 9,10-bis(nitromethy1(anthracene and the title compound. The latter is converted by further action of nitric acid to 9-methy1-10-trinitromethylanthracene, 10-methyl-9-anthrylnitrile oxide, and other oxidation products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d4be574c8df2d19b6d9a3b0102e32ff4 https://doi.org/10.1246/cl.1987.979 Zobrazit plný text záznamu