The effects of functionalization on the thermal and tribo-mechanical behaviors of neat and grafted polyethylene nanocomposites
| Autor: | Aleksandar M. Orlović, Igor Balać, Milorad Zrilić, Radoslav Aleksić, Chak Yin Tang, Petar S. Uskoković, Dušica B. Stojanović |
|---|---|
| Rok vydání: | 2013 |
| Předmět: |
chemistry.chemical_classification
Thermogravimetric analysis Nanocomposite Materials science Polymers and Plastics Composite number 02 engineering and technology General Chemistry Polymer Polyethylene 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Silanization Materials Chemistry Ceramics and Composites Surface modification Fourier transform infrared spectroscopy Composite material 0210 nano-technology |
| Zdroj: | Polymer Composites |
| ISSN: | 0272-8397 |
| DOI: | 10.1002/pc.22574 |
| Popis: | This article presents research on the influence of a coupling agent γ-methacryloxypropyltrimethoxysilane (MEMO) and cross-linking agent dicumyl peroxide (DCP) on thermal and nanomechanical properties of neat and waste polyethylene (WPE) as well as their blend. Modification of nanosilica by silanization was performed under supercritical conditions of carbon dioxide-ethanol mixture. Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), indentation as well as scratch testing at nanoscale were employed for characterization of the polymer matrix with unmodified and modified nano-SiO2 particles. Low amounts of the peroxide and silanized nano-SiO2 particles in the composite formulation significantly improved thermal and tribo-mechanical behavior at nanoscale. POLYM. COMPOS., 34:1710–1719, 2013. © 2013 Society of Plastics Engineers |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
| Nepřihlášeným uživatelům se plný text nezobrazuje | K zobrazení výsledku je třeba se přihlásit. |