Adducts of ArSCl with vinyl ethers or esters as synthones in geminal alkylation

Autor:	Alexei V. Gromov, Elisey Yagodkin, William A. Smit
Rok vydání:	2003
Předmět:	Geminal Chemistry chemistry.chemical_element General Medicine General Chemistry Alkylation Medicinal chemistry Chloride Adduct Reaction sequence Nucleophile medicine Organic chemistry Carbon medicine.drug
Zdroj:	Mendeleev Communications. 13:21-23
ISSN:	0959-9436
DOI:	10.1070/mc2003v013n01abeh001710
Popis:	The in situ-prepared adducts of arylsulfenyl chloride and vinyl ethers (esters) were employed as synthetic equivalents of 1,1-bis-electrophiles in the Lewis acid-promoted reaction sequence with two different carbon nucleophiles resulting in the formation of geminal bisalkylation products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d479d23db4b4412f4ea470415492f9ee https://doi.org/10.1070/mc2003v013n01abeh001710 Zobrazit plný text záznamu Full Text from ScienceDirect