Cu-catalyzed oxidative Povarov reactions between N-alkyl N-methylanilines and saturated oxa- and thiacycles

Autor:	Rai-Shung Liu, Rahul Kisan Kawade, Deepak B. Huple, Rong-Jing Lin
Rok vydání:	2015
Předmět:	Alkane chemistry.chemical_classification Metals and Alloys General Chemistry Oxidative phosphorylation Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Reagent Materials Chemistry Ceramics and Composites Organic chemistry Alkyl
Zdroj:	Chemical Communications. 51:6625-6628
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c5cc01287b
Popis:	Cu-catalyzed oxidative Povarov reactions between N,N-dialkylanilines and saturated oxa- or thiacycles with tert-butyl hydroperoxide (TBHP) are described; notably, the reactions use neither [4π] nor [2π]-motifs as the initial reagents. The use of cheap alkane-based substances as building units is of mechanistic and practical interest as two inert sp(3) C-H bonds are activated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d4776c5c531efcefec15e5acf8a4bb2e https://doi.org/10.1039/c5cc01287b Zobrazit plný text záznamu