Functionalization of Two-Dimensional Coordination Polymer in Small Organic Matter Removal from Organic Wastewater

Autor: Billy Oktora Abdilah Fauzi, Mitsuru Kondo, Mohamed I. Elzagheid, Lydia Rhyman, Ponnadurai Ramasami
Rok vydání: 2022
Předmět:
Zdroj: Journal of Inorganic and Organometallic Polymers and Materials. 32:3488-3495
ISSN: 1574-1451
1574-1443
Popis: Multicobalt(II) two-dimensional layer coordination polymer {[Co(bitbu-OMe)2(NCS)2]·2MeOH}n (1) was synthesized using a bis-imidazole ligand having a steric hindrance, tert-butyl, and one methoxy group expressed by bitbu-OMe (bitbu-OMe = 1,1’-[(5-tert-butyl-2-methoxybenzene-1,3-diyl)dimethanediyl]bis(1H-imidazole). Since there are two methanol molecules trapped inside each void within 1, the investigation of small organic matters removal from organic wastewater was conducted in order to reveal its ability in the purification process. The research findings indicate that 1 has the ability to capture methanol, acetone, acetonitrile, and tetrahydrofuran in organic wastewater with removal ratios of 29.17%, 63.22%, 42.77%, and 21.24%, respectively.
Databáze: OpenAIRE
Externí odkaz: