Dioxirane Oxidations of Compounds other than Alkenes

Autor:	Kavitha Jakka, Waldemar Adam, Cong Gui Zhao
Rok vydání:	2008
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Silanes Double bond chemistry Dioxirane Heteroatom chemistry.chemical_element Organic chemistry Lone pair Deoxygenation Sulfur Group 2 organometallic chemistry
Zdroj:	Oxidation of Organic Compounds by Dioxiranes ISBN: 9780470466759 Organic Reactions
DOI:	10.1002/0471264180.or069.01
Popis:	Epoxidations, heteroatom oxidations, and Y-H insertions constitute the best investigated oxidations by dioxiranes. This article concerns epoxidation of the double bonds in the cumulenes, such as allenes, acetylenes, and arenes; the oxidation of heteroatom functionalities, mainly lone pairs on sulfur, on nitrogen, and on oxygen as the deoxygenation of N-oxides; the oxidation of C = Y functionalities, Y-H insertions such as in C-H alkanes, and Si-H silanes; and the oxidation of organometallic substrates including metal and ligand-sphere oxidation. Keywords: Dioxirane oxidations; Allenes; Alkynes; Arenes; Heteroatom substrates; Alkanes; Silanes; Organometallic compounds; Mechanisms; Nitrogen; Sulfur; Selenium; Phosphorus; Oxygen; Halogens; Method comparisons; Experimental procedures
Databáze:	OpenAIRE
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