Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks
| Autor: | Damien E. Coupry, Petko St. Petkov, Matthew Addicoat, Petra Ágota Szilágyi, Thomas Heine, J Butson, Martin Saunders, Hyunjeong Kim, Charlotte Buckley, Kane M. O'Donnell |
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| Rok vydání: | 2016 |
| Předmět: |
Embedment
Chemistry Metals and Alloys Nanoparticle Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Heterogeneous catalysis 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Nanoclusters Materials Chemistry Ceramics and Composites Density functional theory Metal-organic framework Hydrogen spillover 0210 nano-technology |
| Zdroj: | Coupry, D E, Butson, J, Petkov, P S, Saunders, M, O'Donnell, K, Kim, H, Buckley, C, Addicoat, M, Heine, T & Szilágyi, P Á 2016, ' Controlling embedment and surface chemistry of nanoclusters in metal-organic frameworks ', Chemical Communications, vol. 52, no. 29, pp. 5175-8 . https://doi.org/10.1039/c6cc00659k |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c6cc00659k |
| Popis: | A combined theoretical and experimental approach demonstrates that nanocluster embedment into the pores of metal-organic frameworks (MOF) may be influenced by the chemical functionalisation of the MOF. Furthermore, this results in the surface functionalisation of the embedded nanoclusters, highlighting the potential of MOF scaffolds for the design and synthesis of novel functional materials. |
| Databáze: | OpenAIRE |
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