Methyl 2-diphenylphosphoryloxy-2-azabicyclo[2.2.1]hept-5-ene-3-exo-carboxylate
| Autor: | José E. Rodríguez-Borges, Xerardo García-Mera, Carlos Sousa, Marı́a Luisa C. Vale |
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| Přispěvatelé: | Universidade de Santiago de Compostela. Departamento de Química Orgánica |
| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: |
Crystallography
Bicyclic molecule 010405 organic chemistry Chemistry Mean (C–C) = 0.002 A˚ Phosphor T = 100 K General Chemistry Crystal structure Dihedral angle R factor = 0.035 010402 general chemistry Condensed Matter Physics Bioinformatics Organic Papers 01 natural sciences Medicinal chemistry 0104 chemical sciences Group (periodic table) QD901-999 General Materials Science wR factor = 0.091 Data-to-parameter ratio = 15.8 Single-crystal X-ray study Ene reaction |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 1, Pp o188-o188 (2009) Minerva: Repositorio Institucional de la Universidad de Santiago de Compostela Universidad de Santiago de Compostela (USC) Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela instname Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| Popis: | In the title compound, C20H20NO4P, the dihedral angle between the phenyl rings is 68.52 (7) . In the crystal structure, the molecules are linked by a weak C—H(arene) interaction along [010] involving the phenyl CH group and the phenyl rings. There are no further significant intermolecular interactions This work was supported by the Centro de Investigaçao em Química of the University of Porto. The X-ray data were collected at the Unidade de Raios X, RIAIDT, University of Santiago de Compostela. The authors thank Antonio L. Llamas-Saiz for his help and the Fundaçao para a Ciência e Tecnologia (FCT) and Xunta de Galicia for financial support (grants POCTI/QUI/44471/2002 and 07CSA008203-PR, respectively). CADS thanks the FCT for grant No. SFRH/BD/ 31526/2006 SI |
| Databáze: | OpenAIRE |
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