A simple ketone as an efficient metal-free catalyst for visible-light-mediated Diels–Alder and aza-Diels–Alder reactions
| Autor: | Waldemar Schilling, Jiri Kollmann, Daniel Riemer, Yu Zhang, Tong Zhang, Shoubhik Das |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Ketone 010405 organic chemistry 010402 general chemistry 01 natural sciences 7. Clean energy Pollution Combinatorial chemistry 0104 chemical sciences Catalysis Metal Chemistry chemistry Metal free Homogeneous visual_art visual_art.visual_art_medium Diels alder Environmental Chemistry Engineering sciences. Technology Visible spectrum |
| Zdroj: | Green chemistry : cutting-edge research for a greener sustainable future |
| ISSN: | 1463-9270 1463-9262 |
| DOI: | 10.1039/c9gc00485h |
| Popis: | Diels-Alder reactions are highly effective between electron-rich dienes and electron-poor dienophiles. However, these reactions with electron-rich dienophiles are limited and require forcing conditions. Based on this, an efficient metal-free homogeneous system has been developed for the Diels-Alder reactions between electron-rich dienophiles and dienes under visible-light conditions. Additionally, this catalyst has shown excellent reactivity for aza-Diels-Alder reactions. This simple catalyst is commercially available, non-toxic, and cheap and has shown excellent reactivity which is comparable to and in some cases even better than the reported metal-based catalysts. Finally, the mechanism of this reaction has been proposed based on the experimental evidence. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|