New up-conversion luminescence in molecular cyano-substituted naphthylsalophen lanthanide(iii) complexes

Autor: Ethan A. Hiti, Ana de Bettencourt-Dias, Anne E. V. Gorden, Jorge H. S. K. Monteiro, John D. Gorden, Grant R. Wilkinson, Emily E. Hardy
Rok vydání: 2021
Předmět:
Zdroj: Chemical Communications. 57:2551-2554
ISSN: 1364-548X
1359-7345
Popis: A new naphthylsalophen and its 3 : 2 ligand-to-lanthanide sandwich-type complexes were isolated. When excited at 380 nm, the complexes display the characteristic metal-centred emission for NdIII, ErIII and YbIII. Upon 980 nm excitation, in mixed lanthanide and the Er complexes, Er-centred upconversion emission at 543 and 656 nm is observed, with power densities as low as 2.18 W cm−2.
Databáze: OpenAIRE