New up-conversion luminescence in molecular cyano-substituted naphthylsalophen lanthanide(iii ) complexes
Autor: | Ethan A. Hiti, Ana de Bettencourt-Dias, Anne E. V. Gorden, Jorge H. S. K. Monteiro, John D. Gorden, Grant R. Wilkinson, Emily E. Hardy |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | Chemical Communications. 57:2551-2554 |
ISSN: | 1364-548X 1359-7345 |
Popis: | A new naphthylsalophen and its 3 : 2 ligand-to-lanthanide sandwich-type complexes were isolated. When excited at 380 nm, the complexes display the characteristic metal-centred emission for NdIII, ErIII and YbIII. Upon 980 nm excitation, in mixed lanthanide and the Er complexes, Er-centred upconversion emission at 543 and 656 nm is observed, with power densities as low as 2.18 W cm−2. |
Databáze: | OpenAIRE |
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