Experimental Research on NO2 Viscosity and Absorption for (1-Ethyl-3-methylimidazolium Trifluoroacetate + Triethanolamine) Binary Mixtures
| Autor: | Jie Tian, Xinyu Wang, Peiwen Zhang, Nanxi Jin, Baoyou Liu, Huilong Yang |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Analytical chemistry
Pharmaceutical Science Organic chemistry Mole fraction Analytical Chemistry Viscosity chemistry.chemical_compound QD241-441 Desorption Drug Discovery medicine Physical and Theoretical Chemistry ionic liquid 1-ethyl-3-methylimidazolium trifluoroacetate Atmospheric pressure NO2 absorption Atmospheric temperature range triethanolamine chemistry Chemistry (miscellaneous) Triethanolamine Ionic liquid viscosity Molecular Medicine Absorption (chemistry) medicine.drug |
| Zdroj: | Molecules, Vol 26, Iss 6953, p 6953 (2021) Molecules Volume 26 Issue 22 |
| ISSN: | 1420-3049 |
| Popis: | The viscosity (9.34–405.92 mPa·s) and absorption capacity (0.4394–1.0562 g·g−1) of (1-ethyl-3-methylidazolium trifluoroacetate + triethanolamine) binary blends atmospheric pressure in the temperature range of 303.15–343.15 K and at different mole fractions of [EMIM] [TFA] have been carried out. The molar fraction of [EMIM] [TFA] dependence of the viscosity and absorption capacity was demonstrated. The addition of a small amount of [EMIM] [TFA] into TEA led to rapidly decreased rates of binary blends’ viscosity and absorption capacity. However, the viscosity and absorption of binary blends did not decrease significantly when [EMIM] [TFA] was increased to a specific value. Compared with the molar fraction of the solution, the temperature had no obvious effect on viscosity and absorption capacity. By modeling and optimizing the ratio of viscosity and absorption capacity of ([EMIM] [TFA] + TEA), it is proven that when the mole fraction of [EMIM] [TFA] is 0.58, ([EMIM] [TFA] + TEA) has the best viscosity and absorption capacity at the same time. In addition, at 303.15 K, ([EMIM] [TFA] + TEA) was absorbed and desorbed six times, the absorption slightly decreased, and the desorption increased. |
| Databáze: | OpenAIRE |
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