Mass balance analysis of triclosan, diethyltoluamide, crotamiton and carbamazepine in sewage treatment plants
Autor: | Koya Komori, Yutaka Suzuki, Norihide Nakada, Makoto Yasojima, Yuji Okayasu |
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Rok vydání: | 2010 |
Předmět: |
Environmental Engineering
Toluidines Sewage DEET Crotamiton Waste Disposal Fluid chemistry.chemical_compound medicine Effluent Water Science and Technology Chromatography Molecular Structure business.industry Antipruritics Drug Residues Triclosan Anti-Bacterial Agents Carbamazepine chemistry Insect Repellents Sewage sludge treatment Sewage treatment Anticonvulsants business Sludge Water Pollutants Chemical medicine.drug Waste disposal |
Zdroj: | Water science and technology : a journal of the International Association on Water Pollution Research. 61(7) |
ISSN: | 0273-1223 |
Popis: | The behavior of antibacterial triclosan, insect-repellent diethyltoluamide (DEET), anticonvulsant carbamazepine, and antipruritic crotamiton was investigated at two sewage treatment plants (STPs) to clarify their complete mass balance. Twenty-four-hour flow-proportional composite samples were collected from the influent and effluent of primary and final sedimentation tanks, a biofiltration tank and disinfection tanks. Sludge samples (i.e., activated and excess sludge) and samples of the return flow from the sludge treatment process were collected in the same manner. The analytes in both the dissolved and particulate phases were individually determined by a gas chromatograph equipped with mass spectrometer. Triclosan was dominantly detected in the particulate phase especially in the early stage of treatment (up to 83%) and was efficiently removed (over 90%) in STPs, mainly by sorption to sewage sludge. Limited removal was observed for DEET (55±24%), while no significant removal was demonstrated for crotamiton or carbamazepine. The solid-water distribution coefficients (Kd, n=4) for triclosan (log Kd: 3.7–5.1), DEET (1.3–1.9) and crotamiton (1.1–1.6) in the sludge samples are also determined in this study. These findings indicate the limitations of current sewage treatment techniques for the removal of these water-soluble drugs (i.e. DEET, carbamazepine, and crotamiton). |
Databáze: | OpenAIRE |
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