Hydrogen-bonded supramolecular metal-imidazolate frameworks: gas sorption, magnetic and UV/Vis spectroscopic properties

Autor: Christoph Janiak, Uwe Schilde, Karsten Behrens, Sophie Schönfeld, Holger Müller, Birgit Weber, Anas Alrefai, Suvendu Sekhar Mondal, Katlen Brennenstuhl, Christina Günter, Alexandra Kelling, Hans-Jürgen Holdt, Alexander Wruck, Lawrence Rybakowski, Michael U. Kumke, Carmen Herrman, Sascha Eidner, Philipp Brandt
Rok vydání: 2019
Předmět:
Zdroj: Journal of Inclusion Phenomena and Macrocyclic Chemistry. 94:155-165
ISSN: 1573-1111
1388-3127
Popis: By varying reaction parameters for the syntheses of the hydrogen-bonded metal-imidazolate frameworks (HIF) HIF-1 and HIF-2 (featuring 14 Zn and 14 Co atoms, respectively) to increase their yields and crystallinity, we found that HIF-1 is generated in two different frameworks, named as HIF-1a and HIF-1b. HIF-1b is isostructural to HIF-2. We determined the gas sorption and magnetic properties of HIF-2. In comparison to HIF-1a (Brunauer-Emmett-Teller (BET) surface area of 471m(2) g(-1)), HIF-2 possesses overall very low gas sorption uptake capacities [BET(CO2) surface area=85m(2) g(-1)]. Variable temperature magnetic susceptibility measurement of HIF-2 showed antiferromagnetic exchange interactions between the cobalt(II) high-spin centres at lower temperature. Theoretical analysis by density functional theory confirmed this finding. The UV/Vis-reflection spectra of HIF-1 (mixture of HIF-1a and b), HIF-2 and HIF-3 (with 14 Cd atoms) were measured and showed a characteristic absorption band centered at 340nm, which was indicative for differences in the imidazolate framework.
Databáze: OpenAIRE
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