Counter-current separation of cobalt(II)–nickel(II) from aqueous sulphate media with a mixture of Primene JMT-Versatic 10 diluted in kerosene
| Autor: | M.T. Coll, Ana Maria Sastre, M. Hadj Youcef, N. Belhadj, Agustí Fortuny, Tayeb Benabdallah |
|---|---|
| Přispěvatelé: | Universitat Politècnica de Catalunya. Departament d'Enginyeria Agroalimentària i Biotecnologia, Universitat Politècnica de Catalunya. Departament d'Enginyeria Química, Universitat Politècnica de Catalunya. R2EM - Resource Recovery and Environmental Management |
| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
General Chemical Engineering chemistry.chemical_element Counter current Filtration and Separation 02 engineering and technology Ionic liquid 010501 environmental sciences 01 natural sciences chemistry.chemical_compound 020401 chemical engineering Nickel 0204 chemical engineering Solvent extraction Mixture extractants 0105 earth and related environmental sciences Kerosene Aqueous solution Process Chemistry and Technology Cobalt Enginyeria química::Química física::Dissolucions [Àrees temàtiques de la UPC] General Chemistry Continuous counter-current Sulfate minerals chemistry Sulphate media Nuclear chemistry |
| Zdroj: | UPCommons. Portal del coneixement obert de la UPC Universitat Politècnica de Catalunya (UPC) |
| ISSN: | 1520-5754 0149-6395 |
| DOI: | 10.1080/01496395.2019.1577271 |
| Popis: | This work claims the use of the mixture of Primene®JMT-Versatic 10 [HJMT+·Versatic-] IL diluted in Kerosene as an extractant for cobalt/nickel separation from sulphate media by solvent extraction technique, its application on a continuous counter-current device is possible because the presence of Primene®JMT in the organic phase allows us to maintain the pH of the equilibrated aqueous phase at an almost stable value. The solvent extraction of cobalt and nickel ions is studied as a function of the extractant concentration in the organic phase and the concentration of both metals. By constructing the McCabe–Thiele diagram, we found that four steps are necessary to separate the cobalt(II) from the nickel(II) in sulphate media. A simulated continuous counter-current experiment corroborated the McCabe–Thiele predictions, obtaining a raffinate containing 83% of the inlet nickel with a purity of 99.9%, working with an A:O ratio 1:2 This work was supported by the Spanish Ministry ofEconomy and Competitiveness, MINECO grant number [CTM2017–83581–R]. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|