In Situ Grazing Incidence Small-Angle X-ray Scattering Investigation of Polystyrene Nanoparticle Spray Deposition onto Silicon
| Autor: | Gerd Herzog, Stephan V. Roth, Gunthard Benecke, Shun Yu, Jan Perlich, Adeline Buffet, Gonzalo Santoro, Matthias Schwartzkopf, Johannes F. H. Risch, Berit Heidmann, Wilfried Wurth |
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| Rok vydání: | 2013 |
| Předmět: |
Silicon
Materials science Evaporation Nanoparticle chemistry.chemical_element chemistry.chemical_compound X-Ray Diffraction Scattering Small Angle Electrochemistry Deposition (phase transition) General Materials Science Desiccation Spectroscopy Scattering Temperature Surfaces and Interfaces Condensed Matter Physics Crystallography chemistry Chemical engineering Solvents Nanoparticles Polystyrenes Polystyrene Volatilization Dispersion (chemistry) Layer (electronics) |
| Zdroj: | Langmuir. 29:11260-11266 |
| ISSN: | 1520-5827 0743-7463 |
| DOI: | 10.1021/la402254q |
| Popis: | We investigated the spray deposition and subsequent self-assembly during drying of a polystyrene nanoparticle dispersion with in situ grazing incidence small-angle X-ray scattering at high time resolution. During the fast deposition of the dispersion and the subsequent evaporation of the solvent, different transient stages of nanoparticle assembly can be identified. In the first stage, the solvent starts to evaporate without ordering of the nanoparticles. During the second stage, large-scale structures imposed by the breakup of the liquid film are observable. In this stage, the solvent evaporates further and nanoparticle ordering starts. In the late third drying stage, the nanoparticles self-assemble into the final layer structure. |
| Databáze: | OpenAIRE |
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