Controlled Release of Reactive Gases: A Tale of Taming Carbon Monoxide
| Autor: | Martin B. Johansen, Anne K. Ravn, Troels Skrydstrup |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Chemical technology
catalysis Personal account DERIVATIVES reactors ARYL BROMIDES FLUORIDE carbonylation General Chemistry TMSCF3 Controlled release carbon monoxide Catalysis chemistry.chemical_compound chemistry Chemical engineering Isotopes of carbon IODIDES COMPLEXES isotope labeling EX-SITU GENERATION OXIDATIVE-ADDITION Carbonylation Stoichiometry Carbon monoxide |
| Zdroj: | Ravn, A K, Johansen, M B & Skrydstrup, T 2020, ' Controlled Release of Reactive Gases : A Tale of Taming Carbon Monoxide ', ChemPlusChem, vol. 85, no. 7, pp. 1529-1533 . https://doi.org/10.1002/cplu.202000319 |
| ISSN: | 2192-6506 |
| Popis: | This Personal Account describes the development of air-stable and solid precursors for on-demand release of carbon monoxide. In combination with the development of a two-chamber reactor, COware®, CO liberation can be achieved under safe working conditions, as well as allowing transition metal-mediated carbonylations with stoichiometric carbon monoxide. Particularly appealing is the adaptability of this chemical technology for the preparation of carbon isotope labeled bioactive compounds. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|