Size-Tunable Magnetite Nanoparticles from Well-Defined Iron Oleate Precursors

Autor:	Kyle M. Kirkpatrick, Benjamin H. Zhou, Philip C. Bunting, Jeffrey D. Rinehart
Rok vydání:	2022
Předmět:	Engineering General Chemical Engineering Chemical Sciences Materials Chemistry Nanotechnology Bioengineering General Chemistry Materials
Zdroj:	Chemistry of materials : a publication of the American Chemical Society, vol 34, iss 17
ISSN:	1520-5002 0897-4756
Popis:	The synthesis of iron oxide nanoparticles with control over size and shape has long been an area of research, with iron oleate being arguably the most successful precursor. Issues with reproducibility and versatility in iron oleate-based syntheses remain, however, in large part due to the mutable nature of its structure and stoichiometry. In this work, we characterize two new forms of iron oleate precursor that can be isolated in large quantities, show long-term stability, and have well-defined stoichiometry, leading to reproducible and predictable reactivity. Synthesis with these precursors is shown to produce iron oxide nanoparticles in a tunable size range of 4-16 nm with low size dispersity and properties consistent with magnetite in the superparamagnetic size regime.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1cb17e2a7aab757ef104784b9bf6c0c https://doi.org/10.1021/acs.chemmater.2c02046 Zobrazit plný text záznamu