Cyclisation Reactions Involving Alkyl Enol Ethers
| Autor: | Gilles Lemière, Luisa Lempenauer, Elisabet Duñach |
|---|---|
| Přispěvatelé: | Institut de Chimie de Nice (ICN), Université Nice Sophia Antipolis (... - 2019) (UNS), COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)-COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Côte d'Azur (UCA), Institut Parisien de Chimie Moléculaire (IPCM), Chimie Moléculaire de Paris Centre (FR 2769), Institut de Chimie du CNRS (INC)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), Université Paris sciences et lettres (PSL)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
enol ethers Silylation intramolecular reactions catalysis 010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry General Chemistry 010402 general chemistry 01 natural sciences Enol Organic chemist Lewis acid 0104 chemical sciences chemistry.chemical_compound chemistry Intramolecular force cyclisations Enol ether Organic chemistry [CHIM]Chemical Sciences Reactivity (chemistry) Alkyl |
| Zdroj: | Advanced Synthesis and Catalysis Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2019, ⟨10.1002/adsc.201900478⟩ |
| ISSN: | 1615-4150 1615-4169 |
| DOI: | 10.1002/adsc.201900478⟩ |
| Popis: | International audience; Enol ethers are a fascinating product class and valuable building blocks with versatile reactivities and synthetic applications. With the emergence of silyl enol ethers, the chemistry of simple alkyl enol ethers has received less attention and targeted reviews of their chemistry are scarce. Especially intramolecular reactions under participation of an enol ether function have never been specifically surveyed. The construction of cyclic scaffolds is arguably one of the most important and challenging tasks of the organic chemist and intramolecular cyclisations represent the most straightforward tool to achieve this goal. The potential of enol ether-containing substrates to form oxygenated carbo-and heterocycles is obvious. The purpose of this review is to discuss their particular reactivity and to bring to the reader's attention how their unique properties have been harnessed by organic chemists for the construction of rings. |
| Databáze: | OpenAIRE |
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