Crystal structure of 3-methoxy-4-[2-(thiazol-2-yl)diazen-1-yl]aniline monohydrate
| Autor: | Kittipong Chainok, Nutchanikan Phiromphu, Apisit Songsasen, Tanwawan Duangthongyou |
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| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
crystal structure
Chemistry Hydrogen bond Aromaticity General Chemistry Crystal structure Meth Dihedral angle Condensed Matter Physics hydrogen bonding Medicinal chemistry C—H...π interaction thiazole ring Research Communications lcsh:Chemistry chemistry.chemical_compound Aniline lcsh:QD1-999 thiazole ring azo dye Moiety General Materials Science C—H⋯π interaction Physics::Chemical Physics Benzene |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 3, Pp 354-357 (2019) |
| ISSN: | 2056-9890 |
| Popis: | In the title hydrated azo dye, the benzene and thiazole make a dihedral angle of 4.69 (17)°. In the crystal, hydrogen bonds, C—H⋯π and π–π interactions resulting in the formation of a three-dimensional framework. In the title hydrated azo dye, C10H10N4OS·H2O, the benzene and thiazole, are nearly coplanar, with a dihedral angle between their mean planes of 4.69 (17)°. The aromatic rings on the –N=N– moiety exhibit a trans configuration. The crystal structure features many types of intermolecular interactions involving all the functional groups – strong hydrogen bonds (N⋯H and O⋯H), weak hydrogen bonds (C—H⋯O and C—H⋯N), C—H⋯π and π–π interactions – resulting in the formation of a three-dimensional framework. |
| Databáze: | OpenAIRE |
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