Improvement of hydrogen storage characteristics of Mg by planetary ball milling under H2 with metallic element(s) and/or Fe2O3
| Autor: | Myoung Youp Song, Jean-Louis Bobet, Daniel R. Mumm, Hye Ryoung Park, Sung-Nam Kwon |
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| Přispěvatelé: | Division of Advanced Materials Engineering, Research Center of Advanced Materials Development, Chonbuk National University-Engineering Research Institute, Department of Hydrogen and Fuel Cells, Chonbuk National University, Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Université de Bordeaux (UB), Faculty of Applied Chemical Engineering, Chonnam National University, Department of Chemical Engineering and Materials Science, University of California [Irvine] (UCI), University of California-University of California |
| Rok vydání: | 2011 |
| Předmět: |
Materials science
Hydrogen Alloy Energy Engineering and Power Technology chemistry.chemical_element 02 engineering and technology engineering.material 010402 general chemistry 01 natural sciences Hydrogen storage Metallic element Phase (matter) Fe2O3 Ball mill Renewable Energy Sustainability and the Environment Metallurgy Hydride-forming element [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics H2-storage properties of Mg 0104 chemical sciences Grinding Reactive mechanical grinding Nickel Fuel Technology chemistry engineering Particle size 0210 nano-technology |
| Zdroj: | International Journal of Hydrogen Energy International Journal of Hydrogen Energy, Elsevier, 2011, 36 (5), pp.3521-3528. ⟨10.1016/j.ijhydene.2010.12.059⟩ |
| ISSN: | 0360-3199 |
| Popis: | International audience; Among samples of Mg-Ni, Mg-Ni-5Fe2O3, and Mg-Ni-5Fe, Mg-Ni-5Fe had the highest hydriding and dehydriding rates. For the as-milled Mg-Ni-5Fe alloy and the hydrided Mg-Ni-5Fe alloy after activation, the weight percentages of the constituent phases were calculated using the FullProf program. The creation of defects and the diminution of Mg particle size through reactive mechanical grinding and hydriding-dehydriding cycling, and the formation of the Mg2Ni phase are considered to increase the hydriding and dehydriding rates. Mg-14Ni-2Fe-2Ti-2Mo had higher hydriding and dehydriding rates than did any of the other samples (Mg-Ni, Mg-Ni-5Fe2O3, Mg-Ni-5Fe, and Mg-14Ni-6Fe2O3) prepared in this work. |
| Databáze: | OpenAIRE |
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