Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents†
| Autor: | Daniel A. Singleton, Milton R. Smith, Venkata A. Kallepalli, Philipp C. Roosen, Britt A. Vanchura, Richard J. Staples, Robert E. Maleczka, Sean M. Preshlock |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: |
Models
Molecular Molecular Conformation chemistry.chemical_element Stereoisomerism Electrons Photochemistry Iridium Ligands Borylation Catalysis Molecular conformation Article Materials Chemistry Electronic effect Boron Ligand Metals and Alloys General Chemistry Carbon Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystallography chemistry Ceramics and Composites Hydrogen |
| Popis: | Experiment and theory favour a model of C–H borylation where significant proton transfer character exists in the transition state. |
| Databáze: | OpenAIRE |
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