Synthesis of 1,2 '-Biazulenes by Palladium-Catalyzed Unusual Homocoupling Reaction of 1-Haloazulenes in the Presence of Ferrocene
| Autor: | Taku Shoji, Miwa Tanaka, Kanami Miyashita, Shunji Ito, Tetsuo Okujima, Akifumi Maruyama, Ryuta Sekiguchi, Takanori Araki |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
azulene
010405 organic chemistry Organic Chemistry chemistry.chemical_element Azulene homocoupling 010402 general chemistry Photochemistry 01 natural sciences Redox Catalysis cyclic voltammetry 0104 chemical sciences chemistry.chemical_compound chemistry Ferrocene UV/Vis spectrum Differential pulse voltammetry 1 2 '-biazulene Cyclic voltammetry Spectroscopy Palladium |
| Zdroj: | SYNTHESIS. 48(15):2438-2448 |
| ISSN: | 0039-7881 |
| Popis: | The synthesis of 1,2-biazulenes was established by palladium-catalyzed homocoupling reactions of the corresponding 1-haloazulenes in the presence of ferrocene. The optical properties of the novel 1,2-biazulenes were investigated by UV/Vis spectroscopy and theoretical calculations. The redox behaviors of 1,2-biazulenes were also examined by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). Article SYNTHESIS. 89(11):2438-2448 (2016) |
| Databáze: | OpenAIRE |
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