t-Bu-QuinoxP* Ligand: Applications in Asymmetric Pd-Catalyzed Allylic Substitution and Ru-Catalyzed Hydrogenation

Autor:	Kazuhiro Yoshida, Miwako Nishimura, Tsuneo Imamoto, and Aya Koide
Rok vydání:	2007
Předmět:	Allylic rearrangement Chemistry Stereochemistry Ligand organic chemicals Organic Chemistry Chiral ligand Asymmetric hydrogenation Enantioselective synthesis Noyori asymmetric hydrogenation Enantiomeric excess Asymmetric induction
Zdroj:	The Journal of Organic Chemistry. 72:7413-7416
ISSN:	1520-6904 0022-3263
Popis:	The potential of the t-Bu-QuinoxP* ligand (1) as a chiral ligand in asymmetric synthesis was examined. The ligand exhibited good to excellent asymmetric induction in Pd-catalyzed asymmetric allylic substitution of 1,3-diphenyl-2-propenyl acetate (up to 98.7% ee) and in Ru-catalyzed asymmetric hydrogenation of ketones (up to 99.9% ee).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d0f0f73dcdb984382226b73766a2b3ec https://doi.org/10.1021/jo071192k Zobrazit plný text záznamu