Significance of Dopant/Component Miscibility to Efficient N-Doping in Polymer Solar Cells
Autor: | Han Yan, Baojun Lin, Tao Li, Yabing Tang, Wei Ma, Hanzhang Zhao |
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Rok vydání: | 2020 |
Předmět: |
Materials science
Dopant Component (thermodynamics) Organic devices Doping 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Miscibility Polymer solar cell 0104 chemical sciences Chemical engineering General Materials Science Ternary phase diagram 0210 nano-technology |
Zdroj: | ACS Applied Materials & Interfaces. 12:13021-13028 |
ISSN: | 1944-8252 1944-8244 |
DOI: | 10.1021/acsami.9b21252 |
Popis: | The uncertain dopant location in the bulk heterojunction (BHJ) film hinders the wide application of molecular doping in polymer solar cells (PSCs) as is in other organic devices. It is known that the interaction between the dopant and component governs the dopant distribution in the BHJ film and thus largely controls the effectiveness of molecular doping. After excluding the strong dopant/component interaction by forming the charge-transfer complex in the solution, we estimate the dopant/component miscibility by calculating the difference of Hansen's total solubility parameters (△δ |
Databáze: | OpenAIRE |
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