A phosphorescent fluoride probe based on Eu(ııı )-DO3A clicked with a 2,5-di(thien-2-yl)pyrrole scaffold
| Autor: | Melek Pamuk Algi, Fatih Algi, Aysun Degirmenci, Memduh Bilmez |
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| Přispěvatelé: | Sabire Yazıcı Fen Edebiyat Fakültesi, Algi, Fatih -- 0000-0001-9376-1770, [Bilmez, Memduh -- Degirmenci, Aysun -- Algi, Melek Pamuk -- Algi, Fatih] Aksaray Univ, ASUBTAM Memduh Bilmez BioNanoTech Lab, TR-68100 Aksaray, Turkey -- [Algi, Melek Pamuk] Aksaray Univ, Vocat Sch, Hlth Serv, TR-68100 Aksaray, Turkey -- [Algi, Fatih] Aksaray Univ, Dept Biotechnol & Mol Biol, TR-68100 Aksaray, Turkey |
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Scaffold Inorganic chemistry Alkyne 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Ring (chemistry) 01 natural sciences Catalysis Cycloaddition 0104 chemical sciences chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Azide 0210 nano-technology Phosphorescence Fluoride Pyrrole |
| Zdroj: | New Journal of Chemistry. 42:450-457 |
| ISSN: | 1369-9261 1144-0546 |
| DOI: | 10.1039/c7nj03569a |
| Popis: | WOS: 000418369000048 The design, synthesis and physicochemical properties of a new phosphorescent fluoride probe 1 are described. The probe consists of a stable Eu(III) complex of a DO3A macrocycle on one side and a 2,5-di(thien-2-yl)pyrrole (SNS) scaffold on the other. They were linked together with a 1,2,3-triazole ring as a reliable connection unit, which was formed by Huisgen type copper-catalyzed [3+2] cycloaddition between the corresponding azide and alkyne. This novel material can be used as a turn-on phosphorescent fluoride probe. To the best of our knowledge, this is the first example of the combination of an SNS unit with a clicked Eu(III) complex of DO3A scaffold, which can induce a prominent luminogenic response to fluoride ions among other anions. Finally, its behavior as a two-input OR logic gate was also demonstrated using OH- and OAc- anions. Scientific and Technological Research Council of Turkey (TUBITAK) [112T668]; European Cooperation in Science and Technology (CMST COST Action European F-Element Network (EUFEN)) [CM 1006]; Turkish Academy of Sciences (TUBA) for an Outstanding Young Investigator Award (GEBIP); TUBITAK The authors are grateful to the Scientific and Technological Research Council of Turkey (TUBITAK, Grant No. 112T668) and European Cooperation in Science and Technology (CMST COST Action CM 1006 European F-Element Network (EUFEN)). F. A. is indebted to the Turkish Academy of Sciences (TUBA) for an Outstanding Young Investigator Award (GEBIP). M. B. and A. D. are indebted to TUBITAK for graduate fellowships. F. A. thanks S. Ozcubukcu for providing a small amount of their click catalyst as a gift. |
| Databáze: | OpenAIRE |
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