Facile cyclization of sodium aminodiboranate to construct a boron-nitrogen-hydrogen ring

Autor:	Yanfeng Yue, Jiaxin Kang, Ai-Ju Zhou, Hong-Yu Guan, Mingyue Ju, Huizhen Li, Douglas J. Austin
Rok vydání:	2020
Předmět:	Inorganic Chemistry Chemical substance chemistry Hydrogen Sodium chemistry.chemical_element Dihydrogen bond Ring (chemistry) Science technology and society Boron Nitrogen Combinatorial chemistry
Zdroj:	Dalton transactions (Cambridge, England : 2003). 49(46)
ISSN:	1477-9234
Popis:	A facile and efficient cyclization of sodium aminodiboranate to construct a boron-nitrogen-hydrogen ring is presented. This new strategy can be developed into a general method to prepare aminodiborane and its derivatives. Theoretical calculations show that a one-step cyclization mechanism is favored, where the dihydrogen bond plays an important role.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d0711bd6b019840b25572d6a36413a38 https://pubmed.ncbi.nlm.nih.gov/33196721 Zobrazit plný text záznamu