Directing On‐Surface Reaction Pathways via Metal‐Organic Cu−N Coordination
| Autor: | Huifang Liang, Lifeng Chi, Haiming Zhang, Ziliang Shi, Shuaipeng Xing |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Materials science
02 engineering and technology Surface reaction 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Atomic and Molecular Physics and Optics Coupling reaction 0104 chemical sciences law.invention Metal Polymerization law visual_art visual_art.visual_art_medium Physical and Theoretical Chemistry Scanning tunneling microscope 0210 nano-technology |
| Zdroj: | ChemPhysChem. 21:843-846 |
| ISSN: | 1439-7641 1439-4235 |
| DOI: | 10.1002/cphc.201901210 |
| Popis: | We demonstrate an enhancement of cyclization against polymerization for the on-surface debrominative coupling reaction, by using the metal-organic Cu-N coordination template to direct the reaction pathways. Experiments performed by using ultrahigh-vacuum scanning tunneling microscopy (UHV-STM), with the substitution of metal-coordination centers, metallic substrates and functional organic ligands, corroborate the template effect of the Cu-N coordination. |
| Databáze: | OpenAIRE |
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