A High-Throughput Composite Catalyst based on Nickel Carbon Cubes for the Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran
| Autor: | Nina Fechler, Valerio Molinari, Max Braun, Markus Antonietti, Christian Mbaya Mani |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Nanocomposite
Materials science Organic Chemistry 2 5-Dimethylfuran Composite number chemistry.chemical_element Nanoparticle Nanotechnology 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Heterogeneous catalysis 01 natural sciences Catalysis 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Nickel chemistry Chemical engineering Physical and Theoretical Chemistry 0210 nano-technology Carbon |
| Zdroj: | ChemCatChem |
| ISSN: | 1867-3880 |
| Popis: | A high-throughput composite catalyst is prepared from porous carbon with an unconventional nanocube morphology decorated by nickel nanoparticles. Due to the advantageous properties of the designed carbon support, the composite combines a high surface area and a hierarchical pore structure with high functionality. Furthermore, the regularly shaped nanocubes allow for a good packing of a fixed-bed flow reactor, while the internal transport pores cannot be blocked and stay open for efficient column performance. The composite is employed as catalyst in the hydrogenation of 5 hydroxymethylfurfural (HMF) to 2,5-dimethylfuran showing good catalytic performance and overcoming the conventional problem of column blocking. |
| Databáze: | OpenAIRE |
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