Coexistence of Different Growth Mechanisms of Sodium Chlorate under the Same Experimental Conditions
Autor: | M.M. Mitrović, Branislava M. Vučetić, Milica Milojević, Andrijana A. Žekić, Biljana Z. Maksimović |
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Jazyk: | angličtina |
Rok vydání: | 2021 |
Předmět: |
Supersaturation
Materials science General Chemical Engineering Crystal growth 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Power law Article 0104 chemical sciences Crystal chemistry.chemical_compound Chemistry chemistry Growth parameter Chemical physics Growth rate 0210 nano-technology Dispersion (chemistry) QD1-999 Sodium chlorate |
Zdroj: | ACS Omega, Vol 6, Iss 34, Pp 21909-21914 (2021) ACS Omega |
ISSN: | 2470-1343 |
Popis: | Dependence of growth rates of {100} sodium chlorate crystal faces on solution supersaturation in the range of 0.44-1.32% was analyzed. It has been shown that the growth rate dispersion does not have a consequence only in the growth parameter differences predicted by specific crystal growth theory but that individual crystal faces may grow with different mechanisms under the same experimental conditions. The majority of the observed {100} sodium chlorate crystal faces grew in accordance with the power law R ∼ σ n , whereas approximately one-third of them grew in accordance with BCF or Chernov's theories. Possible reasons for this as well as for the coexistence of crystal faces, which grew with different mechanisms under the same conditions, have been discussed. |
Databáze: | OpenAIRE |
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