High-energy radiation processing, a smart approach to obtain PVP-graft-AA nanogels
Autor: | Natascia Grimaldi, Giuseppe Spadaro, Maria Antonietta Sabatino, Sabina Alessi, I. Kaluska, Donatella Bulone, Maria Luisa Bondì, G. Przybytniak, Clelia Dispenza |
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Přispěvatelé: | Grimaldi, N, Sabatino, MA, Przybytniak, G, Kaluska, I, Bondì, ML, Bulone, D, Alessi, S, Spadaro, G, Dispenza, C |
Rok vydání: | 2014 |
Předmět: |
chemistry.chemical_classification
Poly(N-vinylpyrrolidone) Acrylic acid grafting Nanogels E-beam irradiation Radiation Materials science Aqueous solution Absorption spectroscopy Infrared spectroscopy Polymer chemistry.chemical_compound Monomer chemistry Chemical engineering Polymer chemistry Settore CHIM/07 - Fondamenti Chimici Delle Tecnologie Surface charge Spectroscopy Poly(N-vinylpyrrolidone) acrylic acid grafting nanogels e-beam irradiation Acrylic acid |
Zdroj: | Radiation physics and chemistry (1993) 94 (2014): 76–79. doi:10.1016/j.radphyschem.2013.04.012 info:cnr-pdr/source/autori:N. Grimaldi, M.A. Sabatino, G. Przybytniak, I. Kaluska, M.L. Bondì, D. Bulone, S. Alessi, G. Spadaro, C. Dispenza/titolo:High-energy radiation processing, a smart approach to obtain PVP-graft-AA nanogels./doi:10.1016%2Fj.radphyschem.2013.04.012/rivista:Radiation physics and chemistry (1993)/anno:2014/pagina_da:76/pagina_a:79/intervallo_pagine:76–79/volume:94 |
ISSN: | 0969-806X |
Popis: | Poly(N-vinylpyrrolidone)-grafted-acrylic acid biocompatible nanogels (NGs) were prepared using an exiting industrial-type electron accelerator and setups, starting from semi-dilute aqueous solutions of a commercial PVP and the acrylic acid monomer. As a result, NGs with tunable size and structure can be obtained quantitatively. Sterility was also imparted at the integrated dose absorbed. The chemical structure of the NGs produced was confirmed through Fourier Transformer Infrared Spectroscopy (FT-IR). The molecular and physico-chemical properties of NGs, such as the hydrodynamic dimensions and surface charge densities, for various polymer and monomer concentrations in the irradiated solutions, are discussed here. |
Databáze: | OpenAIRE |
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