Synthesis and thermal properties of bio-based copolyesters from the mixtures of 2,5- and 2,4-furandicarboxylic acid with different diols
| Autor: | Rutger J. I. Knoop, Daan S. van Es, Shanmugam Thiyagarajan, Aurélie Bourdet, Eric Dargent, Jacco van Haveren, Antonella Esposito, Willem Vogelzang, Michael A. Meijlink |
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| Přispěvatelé: | Wageningen Food & Biobased Res, Bornse Weilanden 9, NL-6708 WG Wageningen, Netherlands, Groupe de physique des matériaux (GPM), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU), Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche sur les Matériaux Avancés (IRMA), Université de Caen Normandie (UNICAEN), Normandie Université (NU)-Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Centre National de la Recherche Scientifique (CNRS)-Université de Caen Normandie (UNICAEN), Normandie Université (NU)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
General Chemical Engineering
Bio based 02 engineering and technology Activation energy 010402 general chemistry 01 natural sciences [SPI.MAT]Engineering Sciences [physics]/Materials chemistry.chemical_compound BBP Sustainable Chemistry & Technology Furan Thermal Environmental Chemistry Organic chemistry Biobased Products ComputingMilieux_MISCELLANEOUS VLAG MT-TGA Renewable Energy Sustainability and the Environment General Chemistry 021001 nanoscience & nanotechnology mixing law 0104 chemical sciences Polyester activation energy chemistry [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] 0210 nano-technology FDCA isomers Henkel reaction [PHYS.COND.CM-SCM]Physics [physics]/Condensed Matter [cond-mat]/Soft Condensed Matter [cond-mat.soft] |
| Zdroj: | ACS Sustainable Chemistry & Engineering ACS Sustainable Chemistry & Engineering, American Chemical Society, 2019, pp.18505-18516. ⟨10.1021/acssuschemeng.9b04463⟩ ACS Sustainable Chemistry and Engineering, 7(22), 18505-18516 ACS Sustainable Chemistry and Engineering 7 (2019) 22 ACS Sustainable Chemistry & Engineering, 2019, pp.18505-18516. ⟨10.1021/acssuschemeng.9b04463⟩ |
| ISSN: | 2168-0485 |
| DOI: | 10.1021/acssuschemeng.9b04463⟩ |
| Popis: | Recent works highlighted how interesting are the properties of furan-based polyesters. Most of the attention has been focused on the homopolyester obtained with 2,5-furandicarboxylic acid and ethylene glycol, but other possibilities exist, which could help in tuning the final properties by carefully selecting the nature and proportion of the initial building blocks. This work reports the synthesis and properties (thermal stability, activation energy for thermal decomposition, glass transition temperature, and aptitude to crystallize) of three series of polyesters obtained by combining various amounts of two isomers of furandicarboxylic acid with different linear aliphatic diols, such as ethylene glycol, 1,3-propanediol, and 1,4-butanediol. This approach provided homopolymers and copolymers with high molecular weights, good thermal stability, broad processing windows, and a thermal behavior that can be tuned both in terms of glass transition temperature and crystallinity. In most cases, the mixtures of 2,5- A nd 2,4-isomers obtained during the Henkel disproportionation reaction can be directly used to synthetize furan-based copolyesters with good properties without the downstream processing typically performed to separate the isomers prior to polymerization, which may considerably reduce the time and costs for biomass valorization. |
| Databáze: | OpenAIRE |
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