Structural Rationalisation of Co-crystals Formed between Trithiocyanuric Acid and Molecules Containing Hydrogen Bonding Functionality

Autor:	Venkateswara Rao Pedireddi, Swati Chatterjee, Kenneth D. M. Harris, Anupama Ranganathan, J. PrakashaReddy, C. N. R. Rao, Shinbyoung Ahn, Benson M. Kariuki
Rok vydání:	2005
Předmět:	Hydrogen bond Organic Chemistry Inorganic chemistry General Chemistry Crystal structure Crystal engineering Catalysis law.invention Solvent chemistry.chemical_compound chemistry law Polymer chemistry Dimethylformamide Molecule Crystallization Acetonitrile
Zdroj:	Chemistry - A European Journal. 11:2433-2439
ISSN:	1521-3765 0947-6539
DOI:	10.1002/chem.200400340
Popis:	Crystallisation of trithiocyanuric acid (TTCA) from various organic solvents that have hydrogen bonding capability (acetone, 2-butanone, dimethylformamide, dimethyl sulfoxide, methanol and acetonitrile) leads to the formation of co-crystals in which the solvent molecules are incorporated together with TTCA in the crystal structure. Structure determination by single-crystal X-ray diffraction reveals that these co-crystals can be classified into different groups depending upon the topological arrangement of the TTCA molecules in the crystal structure. Thus, three different types of single-tape arrangements of TTCA molecules and one type of double-tape arrangement of TTCA molecules are identified. In all co-crystals, hydrogen-bonding interactions are formed through the involvement of N-H bonds of TTCA molecules in these tapes and the other molecule in the co-crystal. Detailed rationalisation of the structural properties of these co-crystals is presented.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cfa0a8ed9d620424785931898d54c62a https://doi.org/10.1002/chem.200400340 Zobrazit plný text záznamu Plný text