| Autor: |
Lava R. Kadel, Elvin V. Salerno, David M. Eichhorn |
| Rok vydání: |
2021 |
| Předmět: |
|
| Zdroj: |
IUCrData, Vol 6, Iss 7, p x210690 (2021) |
| ISSN: |
2414-3146 |
| DOI: |
10.1107/s2414314621006908 |
| Popis: |
The synthesis and structure is reported of TpPh,4CNNi(NO3)(EtOH) or [Ni(C30H19BN9)(NO3)(C2H6O)], the first half-sandwich complex of a cyanoscorpionate ligand. The pseudooctahedral coordination sphere of the NiII ion is comprised of a tridentate tris(4-cyano-3-phenylpyrazolyl)borate ligand, a bidentate nitrate ligand and a neutral ethanol ligand. The phenyl substituents on the TpPh,4CN ligand are relatively parallel to the planes of the ethanol and nitrate ligands. An intermolecular hydrogen-bonding interaction is evident between the ethanol OH group and the pyrazole CN substituent. The ethanol ligand was modeled with a 0.572 (13)/0.428 (13) disorder of the methyl C atom. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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