Fabrication of cost-effective, highly reproducible large area arrays of nanotriangular pillars for surface enhanced Raman scattering substrates

Autor: Kumaran Rajeev Kumar, Aldrin Antony, Joaquim Puigdollers, M. K. Jayaraj, K. Hasna
Přispěvatelé: Universitat Politècnica de Catalunya. Departament d'Enginyeria Electrònica, Universitat Politècnica de Catalunya. MNT - Grup de Recerca en Micro i Nanotecnologies
Jazyk: angličtina
Rok vydání: 2016
Předmět:
Metal nanostructureslocalized surface plasmon resonance (LSPR)
Substrateenhancement factor
Fabrication
Materials science
Silicon
Sers
Pyridine
Localized Surface Plasmon Resonance (Lspr)
chemistry.chemical_element
Nanotechnology
02 engineering and technology
Substrate (electronics)
Ag
010402 general chemistry
01 natural sciences
symbols.namesake
General Materials Science
Electrical and Electronic Engineering
Plasmon
Surface enhanced Raman scattering (SERS)
Colloidal Silver
Spectroscopy
Monolayers
Nanoestructures
Física [Àrees temàtiques de la UPC]
business.industry
Enhancement Factor
Metal Nanostructures
Surface Enhanced Raman Scattering (Sers) Substrate
Spectra
021001 nanoscience & nanotechnology
Condensed Matter Physics
Atomic and Molecular Physics
and Optics

0104 chemical sciences
Nanostructures
Hot-Spots
chemistry
symbols
Optoelectronics
Photonics
0210 nano-technology
business
Raman spectroscopy
Silver Electrode
Raman scattering
Electron-beam lithography
Zdroj: Recercat. Dipósit de la Recerca de Catalunya
instname
UPCommons. Portal del coneixement obert de la UPC
Universitat Politècnica de Catalunya (UPC)
ISSN: 2381-3652
DOI: 10.1007/s12274-016-1190-y
Popis: Development of cost-effective, highly reproducible non-conventional fabrication techniques for anisotropic metal nanostructures is essential to realizing potential applications of plasmonic devices, photonic devices, and surface enhanced Raman scattering (SERS) phenomenon based sensors. This report highlights the fabrication of nanotriangle arrays via nanoimprinting to overcome difficulties in creating large-area SERS active substrates with uniform, reproducible Raman signals. Electron beam lithography of anisotropic nanostructures, formation of arrays of nanotriangles in silicon and the transfer of triangular shapes to polymethylmethacrylate (PMMA) sheets via nanoimprinting have not been reported elsewhere. The reuse of silicon masters offers potential for production of low cost SERS substrates. The SERS activity and reproducibility of nanotriangles are illustrated and a consistent average enhancement factor of up to ~2.9 × 1011, which is the highest value reported for a patterned SERS substrate, is achieved.
Databáze: OpenAIRE