Desolvation-Degree-Induced Structural Dynamics in a Rigid Cerium–Organic Framework Exhibiting Tandem Purification of Ethylene from Acetylene and Ethane

Autor: Han Fang, Bin Zheng, Zong-Hui Zhang, Peng-Bo Jin, Hong-Xin Li, Yan-Zhen Zheng, Dong-Xu Xue
Rok vydání: 2022
Předmět:
Zdroj: ACS Applied Materials & Interfaces. 14:44460-44469
ISSN: 1944-8252
1944-8244
DOI: 10.1021/acsami.2c13500
Popis: Due to the industrial requirements for high production and high quality of ethylene, efficient purification of ethylene from acetylene and ethane is of prime importance but challenging. Dynamic metal-organic frameworks (MOFs) have demonstrated intriguing structural dynamics and diverse applications recently. Among them, although a few flexible ones have exhibited interesting ethylene purification capability, rigid ones were yet barely investigated for such purpose. In this regard, a cerium(III)-based MOF was solvothermally synthesized, which is rigid and assembled from rod molecular building blocks associated with coordinative
Databáze: OpenAIRE