Homogenisation devices for the production of miniemulsions
| Autor: | Christian Graillat, Timothy F. L. McKenna, Philippe A. Tanguy, Catherine Lord, Keltoum Ouzineb, Nathalie Lesauze |
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| Přispěvatelé: | Laboratoire de chimie et procédés de polymérisation (LCPP), Centre National de la Recherche Scientifique (CNRS)-École Supérieure Chimie Physique Électronique de Lyon, École Polytechnique de Montréal (EPM), Laboratoire de génie chimique [ancien site de Basso-Cambo] (LGC), Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées |
| Jazyk: | angličtina |
| Rok vydání: | 2006 |
| Předmět: |
General Chemical Engineering
Particle formation 02 engineering and technology 010402 general chemistry Static mixer 01 natural sciences Homogenization (chemistry) Industrial and Manufacturing Engineering law.invention Control theory law Homogenizer Polymerisation chemistry.chemical_classification Applied Mathematics General Chemistry Polymer 021001 nanoscience & nanotechnology 0104 chemical sciences Miniemulsion [CHIM.POLY]Chemical Sciences/Polymers chemistry Chemical engineering Polymerization Rotor stator Particle size 0210 nano-technology Order of magnitude |
| Zdroj: | Chemical Engineering Science Chemical Engineering Science, Elsevier, 2006, 61 (9), pp.2994-3000. ⟨10.1016/j.ces.2005.10.065⟩ |
| ISSN: | 0009-2509 |
| DOI: | 10.1016/j.ces.2005.10.065⟩ |
| Popis: | International audience; The use of static mixers and a high-intensity homogeniser (type rotor–stator) to generate polymerisable miniemulsions was investigated. The results showed that it is possible to make stable, polymerisable dispersions of droplets with an average particle size of the same order as those obtained using ultrasonification in the case of the rotor–stator, and slightly larger with very simple static mixers. Homogenisation times are on the order of 1–4 h when a previously identified stabilisation system is used to form monomer droplets Ouzineb, K., et al., [2004. Stabilization and compartmentalization in miniemulsion polymerization. Journal of Applied Polymer Science 91, 115–124]. An order of magnitude energy balance shows that static mixers can be used to generate droplets using significantly less energy than is needed for the rotor–stator or ultrasonification. Results also show that the two techniques presented here can also be used to generate relatively concentrated polymerisable dispersions. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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