A Multifunctional 3D Supermolecular Co Coordination Polymer With Potential for CO2 Adsorption, Antibacterial Activity, and Selective Sensing of Fe3+/Cr3+ Ions and TNP
| Autor: | Jitao Lu, Lili Liu, Shimei Zheng, Hang Kou, Xishi Tai, Xiaojing Zhou, Mingjun Song |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Coordination polymer
Magnetism TNP 02 engineering and technology 010402 general chemistry 01 natural sciences Ion chemistry.chemical_compound Adsorption Antiferromagnetism QD1-999 sensing Fe3+/Cr3+ Exchange interaction General Chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences Crystallography antibacterial Chemistry chemistry magnetism 0210 nano-technology Antibacterial activity Luminescence CO2 adsorption |
| Zdroj: | Frontiers in Chemistry, Vol 9 (2021) |
| ISSN: | 2296-2646 |
| DOI: | 10.3389/fchem.2021.678993/full |
| Popis: | A 3D supermolecular structure [Co3(L)2 (2,2′-bipy)2](DMF)3(H2O)3 1) (H3L = 4,4′,4″-nitrilotribenzoic acid) has been constructed based on H3L, and 2,2′-bipy ligands under solvothermal conditions. Compound 1 can be described as a (3, 6)-connected kgd topology with a Schläfli symbol (43)2(46.66.83) formed by [Co3(CO2)6] secondary building units. The adsorption properties of the activated sample 1a has been studied; the result shows that 1a has a high adsorption ability: the CO2 uptakes were 74 cm3·g−1 at 273 K, 50 cm3·g−1 at 298 K, the isosteric heat of adsorption (Qst) is 25.5 kJ mol−1 at zero loading, and the N2 adsorption at 77 K, 1 bar is 307 cm3 g−1. Magnetic measurements showed the existence of an antiferromagnetic exchange interaction in compound 1, besides compound 1 exhibits effective luminescent performance for Fe3+/Cr3+ and TNP. |
| Databáze: | OpenAIRE |
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