Novel ion conductive matrix via dehydrocoupling polymerization of imidazolium-type ionic liquid and lithium 9-borabicyclo[3,3,1]nonane hydride

Autor:	Hiroyuki Ohno, Asako Narita, Noriyoshi Matsumi, Wataru Shibayama
Rok vydání:	2006
Předmět:	Chemistry(all) Polymers and Plastics Chemistry Hydride Inorganic chemistry chemistry.chemical_element General Chemistry Condensed Matter Physics 9-Borabicyclo[3.3.1]nonane chemistry.chemical_compound Polymerization Bromide Ionic liquid Materials Chemistry Ionic conductivity Lithium Nonane
Zdroj:	Polymer Bulletin. 57:109-114
ISSN:	1436-2449 0170-0839
DOI:	10.1007/s00289-006-0527-1
Popis:	An ion conductive zwitterionic polymer electrolyte containing borate units was prepared. The polymer was synthesized via dehydrocoupling of lithium 9-borabicyclo[3,3,1]nonane hydride (lithium 9-BBN hydride) with 1,3-dihydroxyethylimidazolium bromide and subsequent anion exchange reaction using lithium bis(trifluoromethylsulfonyl)imide (LiTFSI). The obtained polymer showed the ionic conductivity of 3.4×10-6 Scm-1 at 50 °C in spite of relatively high glass transition temperature (-6 °C).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cedb3636446d57e5e90fd13e5671689f https://doi.org/10.1007/s00289-006-0527-1 Zobrazit plný text záznamu Full text from SpringerLink